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TECHNOLOGY
FOR THE PRODUCTION OF ACETONE DERIVATIVES
(DIACETONEALCOHOL, ISOPHORONE, HEXYLENEGLYCOL, METHYL ISOBUTYL
CARBINOL)
PROCESS
FEATURES
Apart
of MIBK, CONSER, due to his collaboration with SISAS is in position
to offer technologies for production of various acetone derivatives,
including diacetone alcohol (DAA) isophorone (IPHO) hexyleneglycol (HG)
from diacetone alcohol, methyl isobutyl carbinol (MIBC) from MIBK.
REFERENCES
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Company
|
Location |
Capacity
T/y
|
| SISAS |
Italy |
15000 DAA |
| SISAS |
Italy |
6000
IPHO |
| SISAS |
Italy |
8000
HG + MIBC |
PROCESS
DESCRIPTION
The technologies
offered by CONSER are shortly described as follows:
DAA
technology
Acetone is dimerized at low pressure and low temperature in presence
of a basic catalyst in a reactor of tubular type. The crude product
is then purified in a fractionation system comprising the recovery
of non converted acetone, the separation of a fraction containing
mesityl oxide, the separation of pure DAA.
IPHO technology
Acetone is reacted to IPHO in liquid phase, at pressure of about 50
bar, in presence of a basic catalyst. Crude product is then purified
in a fractionation system comprising the recovery of non converted
acetone, the separation of light and heavy ends to yield a purified
IPHO.
HG and MIBC technology
Both products can be produced in the same unit in blocked operation.
HG is produced hydrogenating catalitically DAA at relatively high
pressure.
MIBC is produced by hydrogenating MIBK at nearly identical conditions.
Both products are purified by fractionation.

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